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In this article, we analyze flows of the platinum group metals (PGMs) platinum, palladium, and rhodium and the environmental impacts associated with their supply in Europe. A model of the use of PGMs in Europe has been developed, and this is combined with a model of environmental pressures related to PGM production. Seven industrial sectors and product groups form the main users of PGMs in Europe, comprising the chemical, petroleum, and glass industries; jewelry, dentistry, electronic equipment, and car catalysts. Most relevant environmental impacts of secondary production in Europe and primary PGM production in South Africa, Russia, and Canada are taken into account, including emissions of sulphur dioxide and carbon dioxide and total material requirement. The article quantifies the PGM flows to, from, and within Europe in 2004. The automotive industry is the single largest user of primary PGMs, and catalytic converters represent the major PGM end use. The chemical and glass industries also require large amounts of PGM but rely mostly on secondary metals. The environmental impacts of primary production exceed those of secondary production by far. An analysis of the use of car catalytic converters shows that as a result of efforts to reduce air pollutant emissions in Europe, other negative environmental impacts, such as point-source pollution and mining waste, are occurring elsewhere - for example, at extraction and refining sites in Siberia and South Africa.
Overviewing the European carbon (C), greenhouse gas (GHG), and non-GHG fluxes, gross primary productivity (GPP) is about 9.3 Pg yr-1, and fossil fuel imports are 1.6 Pg yr-1. GPP is about 1.25% of solar radiation, containing about 360 × 1018 J energy - five times the energy content of annual fossil fuel use. Net primary production (NPP) is 50%, terrestrial net biome productivity, NBP, 3%, and the net GHG balance, NGB, 0.3% of GPP. Human harvest uses 20% of NPP or 10% of GPP, or alternatively 1‰ of solar radiation after accounting for the inherent cost of agriculture and forestry, for production of pesticides and fertilizer, the return of organic fertilizer, and for the C equivalent cost of GHG emissions. C equivalents are defined on a global warming potential with a 100-year time horizon. The equivalent of about 2.4% of the mineral fertilizer input is emitted as N2O. Agricultural emissions to the atmosphere are about 40% of total methane, 60% of total NO-N, 70% of total N2O-N, and 95% of total NH3-N emissions of Europe. European soils are a net C sink (114 Tg yr−1), but considering the emissions of GHGs, soils are a source of about 26 Tg CO2 C-equivalent yr-1. Forest, grassland and sediment C sinks are offset by GHG emissions from croplands, peatlands and inland waters. Non-GHGs (NH3, NOx) interact significantly with the GHG and the C cycle through ammonium nitrate aerosols and dry deposition. Wet deposition of nitrogen (N) supports about 50% of forest timber growth. Land use change is regionally important. The absolute flux values total about 50 Tg C yr-1. Nevertheless, for the European trace-gas balance, land-use intensity is more important than land-use change. This study shows that emissions of GHGs and non-GHGs significantly distort the C cycle and eliminate apparent C sinks.
A model of the use of the platinum group metals (PGMs) platinum, palladium, and rhodium in Europe has been developed and combined with a model of the environmental pressures related to PGM production. Compared to the base case presented in Part I of this pair of articles, potential changes in PGM production and use are quantified with regard to cumulative and yearly environmental impacts and PGM resource use, for the period 2005–2020. Reducing sulfur dioxide (SO2) emissions of PGM producer Norilsk Nickel could cut the cumulative SO2 emissions associated with the use of PGMs in Europe by 35%. Cleaner electricity generation in South Africa could reduce cumulative SO2 emissions by another 9%. Increasing the recycling rate of end-of-life catalytic converters to 70% in 2020 could save 15% of the cumulative primary PGM input into car catalysts and 10% of the SO2 emissions associated with PGM production. In 2020, PGM requirements and SO2 emissions would be, respectively, 40% and 22% lower than the base case. Substituting palladium for part of the platinum in diesel catalysts, coupled with a probable palladium price increase, could imply 15% more cumulative SO2 emissions if recycling rates do not increase. A future large-scale introduction of fuel cell vehicles would require technological improvements to significantly reduce the PGM content of the fuel cell stack. The basic design of such vehicles greatly influences the vehicle power, a key parameter in determining the total PGM requirement.