Previous studies showed that using carbon dioxide (CO2) as a raw material for chemical syntheses may provide an opportunity for achieving greenhouse gas (GHG) savings and a low-carbon economy. Nevertheless, it is not clear whether carbon capture and utilization benefits the environment in terms of resource efficiency. We analyzed the production of methane, methanol, and synthesis gas as basic chemicals and derived polyoxymethylene, polyethylene, and polypropylene as polymers by calculating the output-oriented indicator global warming impact (GWI) and the resource-based indicators raw material input (RMI) and total material requirement (TMR) on a cradle-to-gate basis. As carbon source, we analyzed the capturing of CO2 from air, raw biogas, cement plants, lignite-fired power, and municipal waste incineration plants. Wind power serves as an energy source for hydrogen production. Our data were derived from both industrial processes and process simulations. The results demonstrate that the analyzed CO2-based process chains reduce the amount of GHG emissions in comparison to the conventional ones. At the same time, the CO2-based process chains require an increased amount of (abiotic) resources. This trade-off between decreased GHG emissions and increased resource use is assessed. The decision about whether or not to recycle CO2 into hydrocarbons depends largely on the source and amount of energy used to produce hydrogen.
Poor sustainability and increasing economic shortcomings in fossil raw material use besides further technical developments of substitutes lead to a growing potential for CO2-utilisation. Hence, we balanced CO2-based methane and methanol production in a life cycle assessment and identified CO2-utilisation as a greenhouse gas saving method. However, it requires a lot of renewable energy.
In the future, the capacities of renewable SNG (synthetic natural gas) will expand significantly. Pilot plants are underway to use surplus renewable power, mainly from wind, for electrolysis and the production of hydrogen, which is methanated and fed into the existing gas pipeline grid. Pilot projects aim at the energetic use of SNG for households and transport in particular for gas fueled cars. Another option could be the use of SNG as feedstock in chemical industry.
The early stage of development raises the question of whether SNG should be better used for mobility or the production of chemicals. This study compares the global warming potential (GWP) of the production of fossil natural gas (NG) and carbon-dioxide (CO2)-based SNG and its use for car transport versus chemical use in the form of synthesis gas. Since the potential of wind energy for SNG production is mainly located in northern Germany, the consequences by a growing distance between production in the North and transport to the South of Germany are also examined.
The results indicate that CO2-based SNG produced with wind power would lead to lower GWP when substituting NG for both uses in either transport or chemical production. Differences of the savings potential occur in short-distance pipeline transport. The critical factor is the energy required for compression along the process chain.